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Edge Effects In a Spirally Wound Lithium-Ion Battery

Due to the large differences in length scales in a lithium-ion battery, with the thickness of the different layers typically being several orders of magnitude smaller than the extension in the sheet direction, a lithium-ion battery is often well represented by a one-dimensional model. However, the packing and stacking of the battery may cause edge effects which motivate modeling in higher ...

Diffuse Double Layer

At the electrode-electrolyte interface, there is a thin layer of space charge in a diffuse double layer. This may be of interest when modeling devices such as electrochemical capacitors and nanoelectrodes. This tutorial example shows how to couple the Nernst-Planck equations to the Poisson equation, in order to describe diffuse double layer according to a Gouy-Chapman-Stern model. The physics ...

Primary Current Distribution in a Lead-Acid Battery Grid Electrode

This 3D model example demonstrates the use of the Primary Current Distribution interface for modeling current distributions in electrochemical cells. In primary current distribution, the potential losses due to electrode kinetics and mass transport are assumed to be negligible, and ohmic losses are govern the current distribution in the cell. Here you investigate primary current distribution in ...

Soluble Lead-Acid Redox Flow Battery

In a redox flow battery electrochemical energy is stored as redox couples in the electrolyte, which is stored in tanks outside the electrochemical cell. During operation, electrolyte is pumped through the cell and, due to the electrochemical reactions, the individual concentrations of the active species in the electrolyte are changed. The state of charge of the flow battery is determined by ...

Electrochemical Impedance Spectroscopy in a Fuel Cell

A fuel cell unit cell is modeled using the full Butler-Volmer expression for the anodic and cathodic charge transfer reactions. The anodic and cathodic overpotentials depend on the local ionic and electronic potentials, which are obtained from the charge balance equations for ionic and electronic current. A small sinusoidal perturbation of the potential around a given cell voltage is applied and ...

Ohmic Losses and Temperature Distribution in a Passive PEM Fuel Cell

In small PEM fuel cell systems (in the sub-100 W range) no active devices for cooling or air transport are normally used. This is due to the desire to minimize parasitic power losses from pumps and fans, and to reduce the system complexity, size, and cost. The reactants at the cathode are therefore transported by passive convection/diffusion. Also the heat dissipation occurs by passive transport ...

1D Isothermal Lithium-Air Battery

Rechargeable lithium-air batteries have recently attracted great interest mainly due to their high energy density. The theoretical value is about 11400 Wh/kg which is around 10 times greater than the lithium-ion batteries. In this tutorial, discharge of a lithium-air battery is simulated using the *Lithium-ion Battery* interface. The transport of oxygen (from external air) in the porous carbon ...

1D Lithium-Ion Battery Model for Determination of Optimal Battery Usage and Design

This application example is useful for investigation of the following: Voltage, polarization (voltage drop), internal resistance, state-of-charge (SOC), and rate capability, in lithium-ion batteries under isothermal conditions. Some of the listed properties play an important role in battery management systems (BMS) in, for instance, electric and hybrid electric vehicles (see figure). The more ...

Modeling of an Enzyme-Based Biofuel Cell Anode

Enzyme-based biofuel cells (EBFCs) use biomass and specific enzymes known as biocatalysts in order to convert chemical energy into electrical energy. At the anode of an EBFC, the biomass (substrate) is oxidized to produce protons and electrons. Mediators are used in the anode to shuttle the electrons from enzymes to electrodes. At the cathode, the oxidant (oxygen) reacts with the protons and ...

1D Lithium-Ion Battery Model for Internal Resistance and Voltage Loss Determination

This tutorial digs deeper into the investigation of rate capability in a battery and shows how the *Lithium-Ion Battery* interface is an excellent modeling tool for doing this. The rate capability is studied in terms of polarization (voltage loss) or the internal resistance causing this loss. A typical high current pulse test, namely a Hybrid Pulse Power Characterization (HPPC) test, is ...