Keisoku Engineering System Co., Tokyo, Japan
The tertiary current distributions on the wafer in a plating cell are studied in this work. An acid copper sulfate electrolyte composed of CuSO4/5H2O of 2.4 g/L and H2SO4 of 90 g/L is taken into account for copper deposition on the wafer. The solution of shear-plate agitating fluid dynamics is coupled into the calculation of tertiary current distributions. The obtained distributions of tertiary ...
Modeling a Non-Flooding Hybrid Polymer Electrolyte Fuel Cell and Related Diffusion-Migration-Reaction Systems
B.E. McNealy, J.L. Hertz
University of Delaware, Newark, DE, USA
Introduction: Understanding the mass and charge transport behavior of heterogeneous systems that include diffusion, migration, and reaction of ions is important in fuel cells, batteries, and other electrochemical applications. Here, a numerical model for charged species transport and reaction has been developed to simulate the electrochemical behavior of a novel type of “non-flooding” hybrid ...
University of the West Indies, St. Augustine, Trinidad and Tobago
One viable alternative to non-renewable fossil fuels is the fuel cell. A special class of FC i.e. Proton Exchange Membrane Fuel Cell (PEMFC) has been investigated during the present study. Membrane is a very important part of a PEMFC as most ohmic losses occurs here and limits the maximum operating temperature, causes fuel cross over effect and increase electrochemical kinetics losses resulting ...
P. Alotto, M. Guarnieri, and F. Moro
Dipartimento di Ingegneria Elettrica, Università di Padova, Padova, Italy
The proton exchange membrane is a key component in the currently widely studied Proton Exchange Membrane Fuel Cells. In this paper a fully coupled three-dimensional dynamic numerical model of the membrane including all the physically relevant phenomena, i.e. ion transport, hydration-dependent conductivity and thermal effects is presented. The highly non-linear model is discretized by means of the ...
K. Song, and H. Knickle
Department of Chemical Engineering, University of Rhode Island, Kingston Rhode Island, USA
In this paper we present a study of the time dependent analysis of a metal hydride bed (MHB) which provides constant flow to a fuel cell at required power loading and pressure. The hydrogen gas phase pressure, the hydrogen concentration in the metal hydride and the hydrogen desorption rate are consider as key variables in this study. Both the space scale and time scale analysis are performed. ...
Pryor Knowledge Systems, Inc.
Bloomfield Hills, MI
Electroplating is a vital technology widely employed for many technological applications ranging from decorative or anti-corrosion coatings to high precision nanotechnology passive electromagnetic cloaking devices. This 2D Axisymmetric Electroplating Model demonstrates one of the modeling methodologies that can be used to calculate the transient generation of a coating thickness of a deposited ...
Caribbean Industrial Research Institute, Calibration Laboratory, University of the West Indies, St. Augustine, Trinidad and Tobago
The Polymer Electrolyte Membrane fuel cell is one of the most promising green technologies for addressing portable, as well as transportation power needs. However, the science behind the fuel cell, in many regards, is still an enigma, and even more so, with the vast numbers of novel materials created annually; designed to offset issues related to durability, conductivity, cost- effectiveness and ...
R. Hamou, P. Biedermann, M. Rohwerder, and A. Blumeneau
Max-Planck-Institut für Eisenforschung GmbH, Düsseldorf, Germany
The present work focuses on modeling a new experimental technique: Scanning Electro-chemical Potential Microscopy (SECPM), which is used to probe the potential profile of the electric double layer (EDL). We used an electrostatic approach to compute the EDL potential measured within the metallic probe. Also, we investigated the effect of the interaction of the electrode/probe double layers on the ...
W. Booth, J. Schiffbauer, J. Fernandez, K. Kelley, A. Timperman, and B. Edwards
Physics Department, West Virginia University, Morgantown, WV, USA
Chemical Engineering Department, West Virginia University, Morgantown, WV, USA
Chemistry Department, West Virginia University, Morgantown, WV, USA
The steady-state non-equilibrium distributions of two species of mono-valent ions around a charged nanofluidic channel have been examined. Large reservoirs were placed on either side of the nanoscale channel to simulate bulk concentration of ions in a fluid. Results from COMSOL Multiphysics simulations show that the effect of the potential bias across the nanochannel yields a significant ...
Optimization of the Lithium Insertion Cell with Silicon Negative Electrode for Automotive Applications
R. Chandrasekaran, and A. Drews
Research and Advanced Engineering
Ford Motor Company
The US Advanced Battery Consortium (USABC) has established goals for long term commercialization of advanced batteries for electric vehicle applications. In this work, a dual lithium-ion insertion cell with silicon as the negative electrode and an intercalation material as the positive electrode is modeled using COMSOL Multiphysics. Both are composite porous electrodes with binder, void volume ...